The Cole-Cole Law for Critical Dynamics in Glass-Forming Liquids

Within the mode-coupling theory (MCT) for glassy dynamics, the asymptotic low-frequency expansions for the dynamical susceptibilities at critical points are compared to the expansions for the dynamic moduli; this shows that the convergence properties of the two expansions can be quite different. In some parameter regions, the leading-order expansion formula for the modulus describes the solutions of the MCT equations of motion outside the transient regime successfully; at the same time, the leading- and next-to-leading order expansion formulas for the susceptibility fail. In these cases, one can derive a Cole-Cole law for the susceptibilities; and this law accounts for the dynamics for frequencies below the band of microscopic excitations and above the high-frequency part of the alpha-peak. It is shown that this scenario explains the optical-Kerr-effect data measured for salol and benzophenone (BZP). For BZP it is inferred that the depolarized light-scattering spectra exhibit a wing for the alpha-peak within the Gigahertz band. This wing results from the crossover of the von Schweidler-law part of the alpha-peak to the high-frequency part of the Cole-Cole peak; and this crossover can be described quantitatively by the leading-order formulas of MCT for the modulus.Comment: 15 pages, 9 figure

Pressure induced structural and dynamical changes in liquid Si. An ab-initio study

The static and dynamic properties of liquid Si at high-pressure have been studied using the orbital free ab-initio molecular dynamics method. Four thermodynamic states at pressures 4, 8, 14 and 23 GPa are considered. The calculated static structure shows qualitative agreement with the available experimental data. We analize the remarkable structural changes occurring between 8 and 14 GPa along with its effect on several dynamic properties.Comment: 10 pages, 11 figures. Accepted for publication in Journal of Physics: Condensed Matte

Sexual Function in Women Suffering from Aortoiliac Occlusive Disease

AbstractObjective:to describe the sexual function in women suffering aortoiliac occlusive disease (AIOD) and in an age-matched reference group.Patients and methods:thirty-six women suffering from AIOD were included. Twenty were investigated before vascular intervention (untreated) and 16 different women after treatment (treated). Eighteen age-matched women served as areferencegroup. The patients answered a questionnaire including sexual, social and medical questions and a gynaecological examination was performed.Results:untreated patients with AIOD have a significantly impaired physical well-being compared to the other groups (p<0.001). A negative effect of the vascular disease and its treatment on sexual life was experienced by 69% oftreatedcompared to 40% affected amonguntreated(p=0.05). Vulval sensibility was impaired in 44% oftreated, 11% ofuntreatedand 22% ofreferencepatients. Defective anal sphincter function was found in 33% oftreated, 17% ofuntreatedand 6% in thereferencegroup. Those differences were not statistically significant.Conclusions:symptomatic AIOD in women is associated with a significantly impaired physical and sexual well-being. Though limited by size and methodology, the results indicate the possibility of iatrogenic nerve damage

Density fluctuations and single-particle dynamics in liquid lithium

The single-particle and collective dynamical properties of liquid lithium have been evaluated at several thermodynamic states near the triple point. This is performed within the framework of mode-coupling theory, using a self-consistent scheme which, starting from the known static structure of the liquid, allows the theoretical calculation of several dynamical properties. Special attention is devoted to several aspects of the single-particle dynamics, which are discussed as a function of the thermodynamic state. The results are compared with those of Molecular Dynamics simulations and other theoretical approaches.Comment: 31 pages (in preprint format), 14 figures. Submitted to Phys. Rev.

Investigating long-term human ecodynamics in the European Arctic:Towards an integrated multi-scalar analysis of early and mid Holocene cultural, environmental and palaeodemographic sequences in Finnmark County, Northern Norway

Most parts of the Circumpolar Arctic have only discontinuous evidence for long-term human settlement. In contrast, Northern Norway has an unbroken archaeological record that extends back to the early Holocene. Numerous high-resolution archaeological and palaeoenvironmental records have been generated by commercial excavations and surveys, offering archaeologists unique opportunities to investigate long-term human ecodynamics in an Arctic coastal setting. To date, however, deeper analysis of the new datasets has yet to be undertaken. This paper aims to present a new synthesis of early and mid Holocene archaeological and paleoenvironmental sequences for Western Finnmark (11500-2000 cal BP). This enables us to identify three major phases of culture change that broadly correlate with climatic and environmental shifts. We then present emerging results from our multi-scalar analysis of the processes driving these transformations. At supra-regional and regional scales, our palaeodemographic modelling indicates major population events centered around 6000 cal BP and 4000 cal BP. At intra-regional scales, we are identifying spatial clustering of prehistoric settlements into local socio-economic communities. At the scale of local settlements, our analysis of house-pit chronologies is clarifying the degree of simultaneous occupation and re-use. We also draw on recent research into rock art and ritual landscapes in an effort to reconstruct the relationship between settlement clusters and general interaction patterns. Integration of these diverse lines of evidence is generating a vivid picture of thriving Arctic coastal communities, with indications that the timing and pace of cultural responses to climatic and environmental changes were more complex than previously thought